If the item is already marked as Web Item you will not see a prompt to mark the item as Web Item. Your listing will simply be updated with the new images.
This coincides with the Automatic Create New Listing feature in Listing Manager which allows these items to be sent automatically to either Shopify or ShopRW depending on if you have it enabled.
Note: It is possible to create a listing for eBay using this feature but you will be required to edit that listing in Listing Manager before it can be pushed to eBay. This is because there are some options that need to be edited before the item can be sent to eBay.
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How To Add Images Using the Gallery Feature (From Your iDevice’s Library) iOS
How To Add Images To An Item Using A Barcode On The Tag iOS How To Download and Setup The Liberty Photo App for iOS How To Use The Liberty Photo App for iOS Overview Opening The Liberty Photo App iOS How Use The Camera To Add Images To Items By Using Account - Item Number iOS How To Add Images Using the Gallery Feature (From Your iDevice’s Library) iOS Using The Import Feature To Import Photos from iCloud, Dropbox or Google Drive iOS How to Edit A Photo That Is Attached To An Item iOS Editing The Settings Within Liberty Photo App iOS Placing a Watermark Image On Your Pictures iOS Changing Which Server You Want To Connect To iOS